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Distortion parameters of the ferricenium ion from low temperature absorption, MCD and ESR spectra

✍ Scribed by M.D. Rowe; R. Gale; A.J. McCaffery


Publisher
Elsevier Science
Year
1973
Tongue
English
Weight
263 KB
Volume
21
Category
Article
ISSN
0009-2614

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✦ Synopsis


hlCD measurements on [n-CsHs]2FePF,s at 290 and 6Β°K ze used in conjunction with 20Β°K ESR data to obtain quantitative information on the distortion parameters in [nCsHsj2Fe*.

The sharp structure at 6Β°K enables the identification of a number of weak transitions superimposed on the main charge-transfer bands at 15 820 cm-'.


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Absorption specua oi smgk crystds of &SO4 doped wlih Moor and of RbCIOo and (C2 H5)4NCIOJ doped with RcOi h3~ been mcxurcd 31 the hquid-helium temperature. AU spectra show two band systems with pronounced viiratloml strutlures. In Td symmcuy they must correspond fo 'Tz + 'Al chrrrge-transfer electro