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Matrix reactions of P4 and P2 with O3 molecules

โœ Scribed by Lester Andrews; Matthew McCluskey; Zofia Mielke; Robert Withnall


Publisher
Elsevier Science
Year
1990
Tongue
English
Weight
854 KB
Volume
222
Category
Article
ISSN
0022-2860

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The rate constant for the reaction of O(") with H202 was measured as a function of temperature and the [H202]0/[0]0 ratio. The numerical solution of the appropriate rate equations was used to arrive a t a mechanism which adequately describes our results and the rather divergent data in the literatur

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the formation of higher oxides of chlorine such as Cl 2 O 4 , Cl 2 O 6 , and Cl 2 O 7 has been observed [5 -8]. The reaction mechanisms are not understood but may involve the formation of ClO 3 which has recently been observed in an inert matrix [9]. In these systems, ClO 3 can be formed via the add