Matrix Isolation and Computational Study of the Photochemistry of 1,3,2,4-Benzodithiadiazine
โ Scribed by Gritsan, Nina P.; Pritchina, Elena A.; Bally, Thomas; Makarov, Alexander Yu.; Zibarev, Andrey V.
- Book ID
- 126811853
- Publisher
- American Chemical Society
- Year
- 2007
- Tongue
- English
- Weight
- 299 KB
- Volume
- 111
- Category
- Article
- ISSN
- 1089-5639
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๐ SIMILAR VOLUMES
## Abstract The reaction of the phenyl radical **1** with water has been investigated by using matrix isolation spectroscopy and quantum chemical calculations. The primary thermal product of the reaction between **1** and water is a weakly bound complex stabilized by an OHโ โ โ ฯ interaction. This com
## Abstract The UV photolysis of [2.2]paracyclophanโene (3) and benzoโ[2.2]paracyclophanโene (4), matrixโisolated in argon at 10 K, results in the cleavage of the ethano bridge and formation of compounds 5 and 8, respectively. The IR and UV/Vis spectra are compared with __p__โxylylene and the benzy