The spectra of HCl and DC1 molecules trapped in 3 nitrogen matrix were studied in the 100~250cm-L spectral region. Two absorptions were observed for each species: at 154 and 207cm-L for EfCL and at 132 and 162cm-1 for DCI. These &sorption showed monomeric behaviour. They are 'assigned to librationtr
Matrix isolated spectra of HNCO and HNCS in the far infrared
โ Scribed by J.A. Cugley; A.D.E. Pullin
- Publisher
- Elsevier Science
- Year
- 1973
- Tongue
- English
- Weight
- 453 KB
- Volume
- 19
- Category
- Article
- ISSN
- 0009-2614
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โฆ Synopsis
Far-infrared spectra of matrix isolated HNCO, HNCS, DNCO and DNCS in argon, have been examined in the lo-50 cm-' region ot a temperature of 13ยฐK. The intense bands observed are b&t explzked by rotation of the molecule. The moleculesCO~, OCS, Hz0 and DzO have also been examined and discussed briefly.
๐ SIMILAR VOLUMES
Perylene radical cations have been produced via low-energy electron impact of a vapor phase mixture of perylene, argon and carbon tetrachloride. The cations have been trapped and stabilized in an argon matrix at 12 Kin sufficient quantities to observe their infrared (and visible) absorption spectra.