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Matrix elements of general configuration of nonorthogonalized orbitals in state with definite spin

✍ Scribed by I. G. Kaplan; O. B. Rodimova

Publisher
John Wiley and Sons
Year
1973
Tongue
English
Weight
758 KB
Volume
7
Category
Article
ISSN
0020-7608

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✦ Synopsis

Abstract

The expressions for matrix elements of spin‐independent operators F and G with the use of Young operators are obtained in the case of arbitrary nonorthogonalized orbital configuration, including both singly and doubly filled orbitals and corresponding to the definite value of total spin. The formulas obtained do not require a preliminary construction of linear combinations of determinants and turn into known LΓΆwdin formulas in the particular case of fully antisymmetric spatial states.

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