A Breakdown of the Watson-Type Hamiltoni
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K. Yokoyama; W.C. Lineberger; K.M.T. Yamada
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Article
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1996
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Elsevier Science
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English
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A breakdown of the standard Watson-type rotational Hamiltonian was suggested for a molecule with H 2 XYZ structure [S ห. Urban and K. M. T. Yamada, J. Mol. Spectrosc. 160, 279-288 (1993)]. This breakdown is due to a near-resonant interaction between the ground state rotational levels and rotational