✦ LIBER ✦

Mathematical Techniques in the Study of Coriolis Coupling in Tetrahedral XY4 Molecules

✍ Scribed by S. J. Cyvin; J. Brunvoll; B. N. Cyvin

Publisher: Wiley (John Wiley & Sons)
Year: 2010
Weight: 192 KB
Volume: 73
Category: Article
ISSN: 0037-9646
DOI: 10.1002/bscb.19640730114

No coin nor oath required. For personal study only.

✦ Synopsis

Relations between Coriolis coupling coefficients in tetrahedral XY4 molecules are evaluated, using the method of Ca and related matrices. It appears that the Coriolis coupling may be studied in terms of two independent Coriolis coefficients, e.g. CN and <a. For these two quantities explicit equations are deduced, containing atomic masses, vibrational frequencies (in terms of A values), and force constants of the molecule.

📜 SIMILAR VOLUMES

Expressions of Effective Hamiltonian Par

Expressions of Effective Hamiltonian Parameters of XY4Molecules in the Tetrahedral Formalism

✍ A. Mourbat; M. Loëte 📂 Article 📅 1998 🏛 Elsevier Science 🌐 English ⚖ 374 KB

We have derived expressions of second-order effective Hamiltonian parameters of XY4 molecules in the tetrahedral formalism (1992, J. P. Champion et al., "Spectroscopy of the Earth's Atmosphere and Interstellar Medium: Spherical Top Spectra," Academic Press, San Diego). They are written as a function

Mean amplitudes of vibration, shrinkage

Mean amplitudes of vibration, shrinkage effects, and the Coriolis coupling coefficients in ten planar symmetrical XY3-type molecules and ions

✍ K.G. Srinivasacharya; C. Santhamma 📂 Article 📅 1965 🏛 Elsevier Science 🌐 English ⚖ 240 KB

High Resolution IR Study of the Coriolis

High Resolution IR Study of the Coriolis Coupling between ν3and ν9in CH235Cl37Cl

✍ Marcel Snels 📂 Article 📅 1997 🏛 Elsevier Science 🌐 English ⚖ 137 KB

The infrared spectra of the n 3 and n 9 bands of methylene chloride have been recorded both for isotopically pure CH 2 35 Cl 2 and for a natural mixture with a resolution of 0.0025 -0.004 cm 01 ( FWHM ) in the range 600 -800 cm 01 using a Bruker IFS 120 HR Fourier Transform interferometer. The Corio

Vibration-rotation energies of harmonic

Vibration-rotation energies of harmonic and combination levels in tetrahedral XY4 molecules: Analysis of the 2ν2 and ν2 + ν4 bands of 12CH4

✍ Jean-Paul Champion; Gérard Pierre; Hubert Berger; Jean Cadot 📂 Article 📅 1980 🏛 Elsevier Science 🌐 English ⚖ 804 KB

High Resolution IR Study of the Coriolis

High Resolution IR Study of the Coriolis Coupling between ν3and ν9in Methylene Chloride

✍ Marcel Snels 📂 Article 📅 1995 🏛 Elsevier Science 🌐 English ⚖ 139 KB

The infrared spectra of the n 3 and n 9 bands of isotopically pure CH 35 2 Cl 2 have been recorded at a resolution of 0.0025 cm 01 in the range 600-800 cm 01 with a Bruker IFS 120 HR Fourier Transform interferometer. The Coriolis coupling between the two CCl 2 stretching fundamentals n 3 and n 9 has

Coriolis coupling constants of RuO4. The

Coriolis coupling constants of RuO4. The force constants in the isoelectronic series MoO42−, TcO4−, RuO4

✍ A Müller; B Krebs 📂 Article 📅 1968 🏛 Elsevier Science 🌐 English ⚖ 239 KB