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Mass spectrometry of organic compounds of the group V elements. IV—new data on amines, phosphines, arsines and the corresponding acyl derivatives

✍ Scribed by R. G. Kostyanovsky; A. P. Pleshkova; V. N. Voznesensky; Yu. I. Elnatanov

Publisher
John Wiley and Sons
Year
1976
Tongue
English
Weight
788 KB
Volume
11
Category
Article
ISSN
1076-5174

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✦ Synopsis

Abstract

Further investigations have given new data confirming differences in fragmentation under electrol impact of compounds of trivalent nitrogen and other group V elements. These data have been obtained by comparision of the fragmentation of the amines, phosphines, arsines, benzyl derivatives, geminal systems and acyl derivatives. Mass spectra of tetraethyl derivatives of the group IV elements and acetyl triethyl germane have also been taken and compared with the previous ones.

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Mass spectrometry of organic compounds i
Mass spectrometry of organic compounds in the group V elements—I: Straight chain aliphatic derivatives
✍ R. G. Kostyanovsky; V. G. Plekhanov 📂 Article 📅 1972 🏛 John Wiley and Sons 🌐 English ⚖ 584 KB

Hl1),As and (n-C,H,,),As as well as Et,AsBr have been carried out. Deuteroanalogues, metastable transitions and low voltage spectra were used for elucidation of the fragmentation paths. The mass spectra of MeN(CH,), and CD,N(CH,), were studied to analyse the structure of the fragments. The main degr