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Mass spectrometry of organic compounds in the group V elements—I: Straight chain aliphatic derivatives

✍ Scribed by R. G. Kostyanovsky; V. G. Plekhanov

Publisher
John Wiley and Sons
Year
1972
Tongue
English
Weight
584 KB
Volume
6
Category
Article
ISSN
1076-5174

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✦ Synopsis

Hl1),As and (n-C,H,,),As as well as Et,AsBr have been carried out. Deuteroanalogues, metastable transitions and low voltage spectra were used for elucidation of the fragmentation paths. The mass spectra of MeN(CH,), and CD,N(CH,), were studied to analyse the structure of the fragments. The main degradation path of amines, i.e. cc-cleavage, was shown to be untypical for P, As, Sb and Bi derivatives.

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Mass spectrometry of organic compounds o
Mass spectrometry of organic compounds of the group V elements. IV—new data on amines, phosphines, arsines and the corresponding acyl derivatives
✍ R. G. Kostyanovsky; A. P. Pleshkova; V. N. Voznesensky; Yu. I. Elnatanov 📂 Article 📅 1976 🏛 John Wiley and Sons 🌐 English ⚖ 788 KB

## Abstract Further investigations have given new data confirming differences in fragmentation under electrol impact of compounds of trivalent nitrogen and other group V elements. These data have been obtained by comparision of the fragmentation of the amines, phosphines, arsines, benzyl derivative