Mass spectrometry of macroheterocycles. 1. Mass spectra of isomeric bicyclic crown ethers
β Scribed by A. I. Gren'; A. V. Mazepa; A. V. Lobach; N. G. Luk'yanenko; O. S. Timofeev
- Publisher
- Springer US
- Year
- 1991
- Tongue
- English
- Weight
- 340 KB
- Volume
- 27
- Category
- Article
- ISSN
- 0009-3122
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β¦ Synopsis
extract was dried over CaCI 2 and evaporated in vacuo. The residue was purified by column chromatography [silica gel, benzene--ethyl acetate (5:1)] and recrystallized from benzene--heptane to give 1.98 g (48%) of III.
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The collision-activated dissociation (CAD) mass spectra for a series of crown ethers, perfluor0 crown ethers, cryptands and several dicyclohexano substituted crown ethers are reported. The CAD spectra were acquired with a triple quadrupole mass spectrometer, and in some cases spectra were recorded a
The electron-impact, mass-spectrometric behavior of all theoretically possible, positionally isomeric monobenzyl ethers of methyl pento-, hexo-, and 6-deoxyhexo-pyranosides is described, on the basis of 70-and 12-eV mass spectra, Odcuterium-labeling experiments, elemental composition, and metastable