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Mass spectrometry of basic aluminum sucrose octasulfate using fast atom bombardment with a saturated tetramethylammonium ion sample matrix

✍ Scribed by Randall J. Baker


Publisher
John Wiley and Sons
Year
1989
Tongue
English
Weight
224 KB
Volume
24
Category
Article
ISSN
1076-5174

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✦ Synopsis


A fast atom bombardment method to produce stable molecular cations of sucrose octasulfate8-is described. The technique centers on ion exchange of the nonvolatile inorganic aluminum hydroxide cations for more volatile organic tetramethylammonium ions.


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Basic aspects of fast atom bombardment mass spectrometry such as matrix effects, discriminatory effects between positive and negative ion formation, sensitivity, and isotope dilution have been investigated using oligopeptides and amino acid derivatives as model compounds. The matrix selected was fou