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Mass spectrometry in structural and stereochemical problems. CXXXIV. Electron impact induced alkyl and aryl rearrangements in .alpha.-arylidene cyclic ketones

✍ Scribed by Harris, Roger L. N.; Komitsky, Frank.; Djerassi, Carl.

Book ID
127090976
Publisher
American Chemical Society
Year
1967
Tongue
English
Weight
968 KB
Volume
89
Category
Article
ISSN
0002-7863

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πŸ“œ SIMILAR VOLUMES

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## Abstract Corrected relative migratory aptitudes for aryl groups in the electron‐impact‐induced rearrangement of aryl phenyl carbonates have been determined.

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The mass spectra of five aryl (I to V) and four alkylsulfonylthioureas (VI to IX) have been recorded and mechanistic rationalizations are suggested for their principal fragmentation processes. The aryl analogs exhibited peaks in their mass spectra corresponding to skeletal rearrangements with elimin