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Mass Spectrometry in Structural and Stereochemical Problems. CIII. 1 Electron Impact Induced Methyl Migration in Some 2-Arylidene-1-decalones 2

✍ Scribed by Djerassi, Carl; Duffield, A. M.; Komitsky, F.; Tökes, L.


Book ID
127024102
Publisher
American Chemical Society
Year
1966
Tongue
English
Weight
262 KB
Volume
88
Category
Article
ISSN
0002-7863

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Mass spectrometry in structural and ster
✍ A. M. Duffield; Carl Djerassi; R. Neidlein; E. Heukelbach 📂 Article 📅 1969 🏛 John Wiley and Sons 🌐 English ⚖ 346 KB

The mass spectra of five aryl (I to V) and four alkylsulfonylthioureas (VI to IX) have been recorded and mechanistic rationalizations are suggested for their principal fragmentation processes. The aryl analogs exhibited peaks in their mass spectra corresponding to skeletal rearrangements with elimin