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Mass Spectrometry in Structural and Stereochemical Problems. LX. 1 The Electron Impact Induced Fragmentation of Steroidal Dimethylamines 2

✍ Scribed by Pelah, Z.; Williams, D. H.; Budzikiewicz, H.; Djerassi, Carl

Book ID
127376130
Publisher
American Chemical Society
Year
1965
Tongue
English
Weight
693 KB
Volume
87
Category
Article
ISSN
0002-7863

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Mass spectrometry in structural and ster
Mass spectrometry in structural and stereochemical problemsβ€”CLXXIV:1 Electron-impact induced fragmentation of some aryl- and alkylsulfonylthioureas
✍ A. M. Duffield; Carl Djerassi; R. Neidlein; E. Heukelbach πŸ“‚ Article πŸ“… 1969 πŸ› John Wiley and Sons 🌐 English βš– 346 KB

The mass spectra of five aryl (I to V) and four alkylsulfonylthioureas (VI to IX) have been recorded and mechanistic rationalizations are suggested for their principal fragmentation processes. The aryl analogs exhibited peaks in their mass spectra corresponding to skeletal rearrangements with elimin