๐”– Bobbio Scriptorium
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Mass spectrometry at low electron beam energies: A sensitive probe of vibrational excitation

โœ Scribed by V.T. Amorebieta; A.J. Colussi


Publisher
Elsevier Science
Year
1982
Tongue
English
Weight
286 KB
Volume
89
Category
Article
ISSN
0009-2614

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โœฆ Synopsis


It 1s shown that the imgmcnlrttlon palrcrn of fKsH& produced by low-cncrgy clccrron lmprcl mmwrion m ZI modulated beam mass spectrometer IS 3 SCIISI~IVC lunction of 111~ mWd gas kmpcraturc. Under these condltlons, mats spcctromcfry lends 1tsclCqui1c gcncrrdly IO the study of cncrg dcposulon and exchang m processes mvolvmg polyatomlcs


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For metabolic studies the fragmentation of a novel endothelin receptor antagonist, Bosentan, was investigated using ionspray tandem mass spectrometry. Bosentan belongs to the sulphonamide class and a complicated and unexpected fragmentation at low energy, involving a radical fragmentation of an even