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Mass spectrometric study of the formaldehyde and hydroxymethylene dications

✍ Scribed by D. Stahl; F. Maquin

Publisher
Elsevier Science
Year
1984
Tongue
English
Weight
262 KB
Volume
106
Category
Article
ISSN
0009-2614

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✦ Synopsis

The hydroxymethylene dication HCOH'+ IS shown to be stable in the gas phase, while the isomeric formaldehyde dication is not.The energetics of formation and decomposition of the former is determined from MIKE (mass-analyzed ion kinetic energy) experiments. The esperimental fmdings are shown to be in pleasing sgeement with results from ab initio molecule orbital ~Iculations.

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