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Mass spectrometric studies—II: Mass spectrometric studies of maleimides and benzaldazine adducts. Identification of solid mixtues

✍ Scribed by S. W. Tam

Publisher
John Wiley and Sons
Year
1973
Tongue
English
Weight
306 KB
Volume
7
Category
Article
ISSN
1076-5174

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✦ Synopsis

Abstract

It has been found by mass spectrometric studies that the so‐called ‘1:1‐adduct’ formed by N‐( __n__butyl)maleimide and benzaldazine, is in fact a solid mixture of one part bis‐imide L and one part benzaldazine. Bis‐imide L is one of the three stereoisomeric products obtained by the addition of two mole of N‐( n‐butyl)malemide and one mole of benzaldazine. The three stereoisomeric bis‐imides gave identical mass spectra. Mass spectra of bis‐imide M and bis‐imide M‐ __d__2 are discussed, and confirm the proposed structures of perhydroprazolo‐pyrazole derivatives for these 1:2‐adducts.

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