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Mass spectrometric study of hexamethyldisilazane and some of its N-substituted derivatives

✍ Scribed by J. Tamás; P. Miklós

Publisher
John Wiley and Sons
Year
1975
Tongue
English
Weight
393 KB
Volume
10
Category
Article
ISSN
1076-5174

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✦ Synopsis

Abstract

The electron‐impact‐induced decomposition of the title compounds has been investigated in detail. Deuterium labelling was used to study the mechanisms of fragmentation and the structures of ions generated. Hydrogen, methyl and phenyl group migrations to one of the silicon atoms were observed as significant secondary processes. These processes are usually γ‐transitions, from which it is inferred that these rearrangements occur via 4‐membered cyclic transition complexes.

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