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Mass spectrometric investigation of the kinetics and mechanism of the gas phase and heterogeneous catalytic decomposition of perchloric acid in mixtures of hydrogen, methane, and ammonia

✍ Scribed by O. P. Korobeinichev; G. I. Anisiforov; M. M. Polyakov


Book ID
112422293
Publisher
Springer
Year
1973
Tongue
English
Weight
508 KB
Volume
22
Category
Article
ISSN
1573-9171

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## Abstract The kinetics of the thermal decomposition reaction of gaseous 3,3,6,6‐tetramethyl‐1,2,4,5‐tetroxane (ACDP) in the presence of __n__‐octane was studied in the 403.2–523.2 K temperature range. This reaction yields acetone as the organic product. Under optimum conditions, first‐order kinet