The mass spectra of a number of the epimeric 1,2-dimethyl-4-alkyl-4-hydroxydecahydroquinolines (alkyl: C z C H , CH=CH,, C,H, and COCH,) have been studied. The configuration at C-2 and C-4 in these molecules is proposed on the basis of the data obtained. Some aspects of the fragmentation pathways un
โฆ LIBER โฆ
Mass spectrometric investigation of stereosomeric 1,2-dimethyl-4-substituted decahydroquinol-4-ol N-oxides. Concerning the configuration of the asymmetric nitrogen atom
โ Scribed by V. G. Zaikin; A. A. Bakaev; N. S. Wulfson; A. A. Akhrem; L. I. Ukhova; N. F. Marchenko
- Publisher
- John Wiley and Sons
- Year
- 1977
- Tongue
- English
- Weight
- 498 KB
- Volume
- 12
- Category
- Article
- ISSN
- 1076-5174
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The configuration at C-2 and C-4 in the molecules of 2-methyl-and 1,2-dimethyl-4-vinylethinyl(n-butyl)-4-hydroxyperhydroquinolines was determined by mass spectrometry The principal conclusions concerning the stereochemistry were made on the basis of differences in the values of the I[H-151+/I[xl+.,