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Mass spectrometric determination of the configuration of the 4-substituted 1,2-dimethyl-4-hydroxydecahydroquinolines

✍ Scribed by V. G. Zaikin; N. S. Wulfson; V. I. Zaretskii; A. A. Bakaev; A. A. Akhrem; L. I. Ukhova; N. F. Uskova

Publisher
John Wiley and Sons
Year
1969
Tongue
English
Weight
320 KB
Volume
2
Category
Article
ISSN
1076-5174

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✦ Synopsis

The mass spectra of a number of the epimeric 1,2-dimethyl-4-alkyl-4-hydroxydecahydroquinolines (alkyl: C z C H , CH=CH,, C,H, and COCH,) have been studied. The configuration at C-2 and C-4 in these molecules is proposed on the basis of the data obtained. Some aspects of the fragmentation pathways under electron-impact are discussed.

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