Mass spectrometric investigation of bimolecular compounds

✍ Scribed by George W. Heunisch; Gary W. Keen

• Publisher: John Wiley and Sons
• Year: 1971
• Tongue: English
• Weight: 500 KB
• Volume: 5
• Category: Article
• ISSN: 1076-5174
• DOI: 10.1002/oms.1210051105

✦ Synopsis

Two points involving molecular structure have been investigated using mass spectrometry. First, mass spectra have been obtained that indicate a rapid means for differentiating bimolecular compounds from other structural isomers. Second, the mass spectrometric method has been used to evaluate bonding within bimolecular compounds. Quinone compounds have been reacted with dihydroxybenzene compounds to produce quinhydrone products, and upon mass spectrometric analysis, the quinhydrones decompose to regenerate derivatives of the starting materials. Evaluation of the decomposition products suggests that the hydroxyl hydrogens are involved in a resonance structure, and while in symmetrical quinhydrones, the hydroxyl hydrogens are probably associated equally with each reactant, unsymmetrical quinhydrones generate an unbalanced electronic distribution that eliminates the complete equivalency of the hydrogens.