The rdt, cocii~c~cnts and product eon dlsrrlbutlons for rhc reactions ot OH\* and tlzO+ u ith N2\_ 02 h'0 X20 Xc, CO, CO? H2S Jnd 112 hd\c been dctermlned it 194 + 2 K usmg a selcctcd ton ilo\. rubc (SIFT) dppclrnrus These reactIons urre generally found to proLccd b\~ athcr proton or charge trsnsfcr
Mass spectrometric detection of dioxirane, H2COO, and its decomposition products, H2 and CO, from the reaction of ozone with ethylene
β Scribed by Richard I. Martinez; Robert E. Huie; John T. Herron
- Publisher
- Elsevier Science
- Year
- 1977
- Tongue
- English
- Weight
- 238 KB
- Volume
- 51
- Category
- Article
- ISSN
- 0009-2614
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β¦ Synopsis
Diovirane has been detected in the gas phase, by means of photoionization mass spectromctry, as a product of the low temperature reaction of ozone with ethylene. Hydrogen and carbon monoxide are found to be products of the decomposition of dioxirane. The significance of these observations to atmospheric chemistry is discussed.
π SIMILAR VOLUMES
Fluorescence excitation and dispersed fluorescence spectra of the jz 'E-A 2A, transition of the trifluoromethoxy radical have been measured using laser excitation in the range 336-358 in. The spectra are dominated by the features of the CO stretching and the OCF deformation mode. The LIF technique h