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Mass spectral study of derivatives of 2-aryloxy-2-methylpropanoicacids

โœ Scribed by M. Vairamani; K. V. Siva Kumar; G. K. Viswanadha Rao

Publisher
John Wiley and Sons
Year
1992
Tongue
English
Weight
245 KB
Volume
27
Category
Article
ISSN
1076-5174

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โœฆ Synopsis

Electron impact mass spectra are reported for series of 2-aryloxy-Zmethylpropanoic acids, 2-aryloxy-2methylpropanamides and N-phenyl-2-aryloxy-2-methylpropanamides. Fragmentation mechanisms are discussed on the basis of deuterium labelling, metastable ions and accurate mass measurements.

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Mass spectral analyses of 2-sila-l,2-dihydronaphthalene derivatives are reported. The 2-silanaphthalene radical cations, Zsilanaphthyl cation, 1-sifaindenyl cation, indene radical cation, and indenyl cation were proposed among the fragments of these molecules. The important fragmentation pathways co