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Mass spectral studies of unsymmetrical dialkyl disulfides. Intramolecular 1,2-, 1,3-, and 1,4-hydrogen migration processes

✍ Scribed by Alonso, Miguel E.; Aragona, Horacio; Chitty, A. Wladimir; Compagnone, Reynaldo; Martin, Gonzalo


Book ID
127122880
Publisher
American Chemical Society
Year
1978
Tongue
English
Weight
608 KB
Volume
43
Category
Article
ISSN
0022-3263

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Synthesis of 2-Alkylidene-3,3-dialkyl-1,4-dithianes and Their Oxathiane Analogues by 1,2-Sulfur Migration. -Base-promoted mesylation of tertiary alcohols such as (I) and (III) derived from dithianes or oxathianes results in rearrangement by sulfur migration to yield the 1,4-dithianes (II) and their