Mass spectra of transition metal π-complexes. VI—The metastable ion mass spectrum of (η1-Toluene)-tricarbonylchromium
✍ Scribed by R. Davis; M. L. Webb; D. S. Millington; V. Parr
- Publisher
- John Wiley and Sons
- Year
- 1979
- Tongue
- English
- Weight
- 177 KB
- Volume
- 14
- Category
- Article
- ISSN
- 1076-5174
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✦ Synopsis
First field free region metastable fragmentations of (q6-PhCH3)Cr(C0), have been examined by means of the l i e d scan technique. The molecuiar ion is shown to fragment exciusively by shgie and muitiple CO loss. ' b e ion [C,&CI(CO)~]+' siso fragments direcüy to [C,&Crl+'.
📜 SIMILAR VOLUMES
Fragmentation of the acetyl-and propionyl-ferrocenes under electron impact together with the rupture of C-CO bonds, characteristic of ketones, also includes elimination of water and migration of the OH group to the central metal atom, which is due to keto-enol tautomerization of the acyl group in mo