Mass spectrometry of π-complexes of transition metals. XIII—The dehydration process and genesis of ions [M–O]+⋅ in the mass spectra of cymantrenyl-, ferrocenyl-and benchrotrenylcarbinols

Mass spectrometry of π-complexes of tran

Mass spectrometry of π-complexes of transition metals 38—keto-enol tautomerization of molecular ions of acetyl- and propionyl-ferrocenes in the gas phase

✍ Dmitrii V. Zagorevskii; Tatyana V. Volkova; Sergey O. Yakushin; Boris G. Antipov 📂 Article 📅 1991 🏛 John Wiley and Sons 🌐 English ⚖ 231 KB

Fragmentation of the acetyl-and propionyl-ferrocenes under electron impact together with the rupture of C-CO bonds, characteristic of ketones, also includes elimination of water and migration of the OH group to the central metal atom, which is due to keto-enol tautomerization of the acyl group in mo