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Mass spectra of tert-butyldimethylsilyl ether derivatives of the major metabolite of prostaglandin F

✍ Scribed by Aldo Ferretti; Vincent P. Flanagan

Publisher
Elsevier Science
Year
1996
Tongue
English
Weight
345 KB
Volume
83
Category
Article
ISSN
0009-3084

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✦ Synopsis

The El mass spectra of four tert-butyldimethylsilyl ether derivatives of the major metabolite of prostaglandins Fl~ and F2~ (PGF-M) are presented and discussed. Proposed ion assignments and fragmentation pathways are based on substituent shifts, on data from a deuterium-labeled methoxime analog, and on the analysis of collision-induced dissociation spectra of selected ions. Fragment ions suitable for identification and quantification work are proposed.

πŸ“œ SIMILAR VOLUMES

Mass spectra of n-butylboronate ester de
Mass spectra of n-butylboronate ester derivatives of the major metabolite of prostaglandin F
✍ Aldo Ferretti; Vincent P. Flanagan; John M. Roman πŸ“‚ Article πŸ“… 1994 πŸ› John Wiley and Sons 🌐 English βš– 462 KB

## Abstract The EI mass spectra of six __n__‐butylboronate ester derivatives of the major metabolite of prostaglandins F~1Ξ±~ and F~2Ξ±~ (PGF‐M) are presented and discussed. Proposed ion assignments and fragmentation pathways are based on substituent shifts, on data from a deuterium‐labeled methoxime