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Masked Imidazolyl−Dipyrromethanes in the Synthesis of Imidazole-Substituted Porphyrins

✍ Scribed by Bhaumik, Jayeeta; Yao, Zhen; Borbas, K. Eszter; Taniguchi, Masahiko; Lindsey, Jonathan S.


Book ID
115491143
Publisher
American Chemical Society
Year
2006
Tongue
English
Weight
420 KB
Volume
71
Category
Article
ISSN
0022-3263

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📜 SIMILAR VOLUMES


One-flask synthesis of meso-substituted
✍ Chang-Hee Lee; Jonathan S. Lindsey 📂 Article 📅 1994 🏛 Elsevier Science 🌐 French ⚖ 985 KB

The reaction at room temperature of an aldehyde with excess pyrrole in the absence of solvent affords the meso-substituted dipyrromethane. The reaction is catalyzed with trifluoroacetic acid or with BF9,0(Et)2. The dipyrromethaue is purified by crystallixation or by flash chromatography on silica wi