Marsdenosides A—H, Polyoxypregnane Glycosides from Marsdenia tenacissima.
✍ Scribed by Jun Deng; Zhixin Liao; Daofeng Chen
- Publisher
- John Wiley and Sons
- Year
- 2005
- Weight
- 20 KB
- Volume
- 36
- Category
- Article
- ISSN
- 0931-7597
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## Abstract Two new polyoxypregnane glycosides, marsdenosides L and M (**1** and **2**, resp.), along with five known polyoxypregnane glycosides, **3**–**7**, were isolated from the stem of __Marsdenia tenacissima__ (Roxb.) Wight et Arn. (Asclepiadaceae). The structures and relative configurations
## Abstract Three new polyoxypregnane glycosides, marsdenosides I–K (**1**–**3**), were isolated from the stem of __Marsdenia tenacissima.__ The structures were elucidated on the basis of in‐depth spectroscopic analyses, and by means of chemical evidence. Marsdenoside I (**=** (3__β__,5__α__,11__α_
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Four new pregnane glycosides, tenacigenosides A -D (1 -4), along with six known pregnane aglycones and five known pregnane glycosides, were isolated from the stems of Marsdenia tenacissima (ROXB.) WIGHT et ARN. (Asclepiadaceae). The chemical structures of the new compounds were established by 1D-and