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Many-membered Carbon Rings. XVI. Acetolysis of 5,5-Dimethylcyclononanol Tosylate 1,2

✍ Scribed by Blomquist, A. T.; Meinwald, Yvonne C.


Book ID
126111175
Publisher
American Chemical Society
Year
1958
Tongue
English
Weight
394 KB
Volume
80
Category
Article
ISSN
0002-7863

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On the acetolysis of /exo - and /endo-bi
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Although good evidence has been found for ancbimerlc rmsistaace in the solvolytic reactions of unsaturated systems such as the 2-norbornen-~1 tosylates be,,/ kendo = 8 X 10')' and the 'I-isopropylidene 5-norbornen-2-yl tosylates', the smaller rate factor observed with saturated l ystomb such as the