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Manifestation of the Ferroelectric Phase Transition in the Mössbauer Parameters of the System (SnxPb1−x)2P2S6

✍ Scribed by Baltrünas, D. ;Mikaitis, R. ;Slivka, V. Yu. ;Vysochanskii, Yu. M.


Publisher
John Wiley and Sons
Year
1990
Tongue
English
Weight
328 KB
Volume
119
Category
Article
ISSN
0031-8965

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The Miissbauer spectra of iron and cobalt fluoroborate hexahydrate show a change by a factor of two in the quadrupole interaction near 2%) K and 185 K, respectively, togtther with a sudden drop in resonance fraction. This behaviour is explained as a first order phase transition in which the axial pa