Manganese(III) Acetate Initiated Oxidative Free Radical Reaction between Benzoylindoles and Dimethyl Malonate
โ Scribed by Chuang, Che-Ping; Wang, Sheouw-Fong
- Book ID
- 118268550
- Publisher
- Japan Institute of Heterocyclic Chemistry
- Year
- 1997
- Tongue
- English
- Weight
- 433 KB
- Volume
- 45
- Category
- Article
- ISSN
- 0385-5414
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Absbuctz The manganese(ll1) initiated oxidadve free mlical reaction between 1,4-nqhthoquinme and a-bemyl makmtes giving benzo[alanthmpinones is descriW. Recently, there has been a growing interest in the application of free radical cyclization reactions to the formation of ring systems.1 Benz.o[a]a
The manganese(III) initiated oxidative free radical reaction between 1,4-naphthoquinones and o~-alkylmalonates is described. Benzo[a]anthraquinones, benzo[f]indole-4,9-diones and naphtho [2,3-b] furan-4,9-diones can be prepared effectively from readily available 1,4-naphthoquinones and ~alkylmalonat