Manganese(III) acetate initiated oxidative free radical reaction between N-aroylindoles and dimethyl malonate
โ Scribed by Che-Ping Chuang; Sheow-Fong Wang
- Publisher
- Elsevier Science
- Year
- 1994
- Tongue
- French
- Weight
- 128 KB
- Volume
- 35
- Category
- Article
- ISSN
- 0040-4039
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Absbuctz The manganese(ll1) initiated oxidadve free mlical reaction between 1,4-nqhthoquinme and a-bemyl makmtes giving benzo[alanthmpinones is descriW. Recently, there has been a growing interest in the application of free radical cyclization reactions to the formation of ring systems.1 Benz.o[a]a
The manganese(III) initiated oxidative free radical reaction between 1,4-naphthoquinones and o~-alkylmalonates is described. Benzo[a]anthraquinones, benzo[f]indole-4,9-diones and naphtho [2,3-b] furan-4,9-diones can be prepared effectively from readily available 1,4-naphthoquinones and ~alkylmalonat