By Ursula B i e r m a n n a n d J . 0 . M e t z g e r \* \*
Manganese(III) acetate induced radical addition of azide to unsaturated fatty compounds
✍ Scribed by Biermann, Ursula; Linker, Ursula; Metzger, Jürgen O.
- Book ID
- 118758273
- Publisher
- John Wiley and Sons
- Year
- 2013
- Tongue
- English
- Weight
- 157 KB
- Volume
- 115
- Category
- Article
- ISSN
- 1438-7697
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📜 SIMILAR VOLUMES
Unsaturated fatty acids such as oleic acid are 1,2-dialkyl substituted alkenes, which can be functionalized by free radical addition to the C,Cdouble bond. We have been able to add enolizable compounds, e. g. acetone, acetic acid and malonic acid to methyl oleate mediated by manga- nese(II1)acetate.
Et 3 B-catalysed addition of diphenylphosphine oxide to unsaturated compounds, alkenes, unsaturated acids, allylic alcohols, and allylic a-O-acetyl nitriles constitutes a practical route to a variety of functionalized diphenylphosphine oxides. The very mild conditions employed, together with the sho
## Abstract Manganese(III) acetate catalyzed oxidative radical‐addition reactions of __α__‐dicarbonyl compounds such as methyl acetoacetate (**6**), acetylacetone (**7**), and dimedone (**8**) to the mixture of 1‐ and 2‐phenylcyclohepta‐1,3,5‐triene (**4** and **5**) were investigated (__Scheme 1__