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Lewis Acid Induced Additions to Unsaturated Fatty Compounds III: Alkylaluminium Halide Induced Friedel-Crafts Acylations of Unsaturated Fatty Compounds

✍ Scribed by Biermann, Ursula ;Metzger, J. O.

Publisher
John Wiley and Sons
Year
1992
Weight
309 KB
Volume
94
Category
Article
ISSN
0931-5985

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✦ Synopsis

By Ursula B i e r m a n n a n d J . 0 . M e t z g e r * *

πŸ“œ SIMILAR VOLUMES

Lewis Acid Catalyzed Additions to Unsatu
Lewis Acid Catalyzed Additions to Unsaturated Fatty Compounds. II: Alkylaluminium Halide Catalyzed Ene Reactions of Unsaturated Fatty Compounds and Formaldehyde
✍ Biermann, Ursula ;Metzger, J. O. πŸ“‚ Article πŸ“… 1991 πŸ› John Wiley and Sons βš– 282 KB

We are presenting our results on the alkylaluminium halide catalyzed ene addition of formaldehyde to readily available unsaturated fatty compounds to give primary homoallylic alcohols. The reaction of oleic acid and 10-undecenoic acid with formaldehyde gives (E)-S(lO)-(hydroxyrneth~ yI)octadec-l0(8)