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Lewis Acid Induced Additions to Unsaturated Fatty Compounds

✍ Scribed by Biermann, Ursula ;Metzger, Jürgen O.

Publisher
John Wiley and Sons
Year
1993
Weight
261 KB
Volume
95
Category
Article
ISSN
0931-5985

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✦ Synopsis

By Ursula B i e r m a n n a n d J i i r g e n 0 . M e t z g e r *

📜 SIMILAR VOLUMES

Lewis Acid Catalyzed Additions to Unsatu
Lewis Acid Catalyzed Additions to Unsaturated Fatty Compounds. II: Alkylaluminium Halide Catalyzed Ene Reactions of Unsaturated Fatty Compounds and Formaldehyde
✍ Biermann, Ursula ;Metzger, J. O. 📂 Article 📅 1991 🏛 John Wiley and Sons ⚖ 282 KB

We are presenting our results on the alkylaluminium halide catalyzed ene addition of formaldehyde to readily available unsaturated fatty compounds to give primary homoallylic alcohols. The reaction of oleic acid and 10-undecenoic acid with formaldehyde gives (E)-S(lO)-(hydroxyrneth~ yI)octadec-l0(8)

New Results of Free Radical Additions to
New Results of Free Radical Additions to Unsaturated Fatty Compounds
✍ Metzger, J. O. ;Linker, Ursula 📂 Article 📅 1991 🏛 John Wiley and Sons ⚖ 435 KB

Unsaturated fatty acids such as oleic acid are 1,2-dialkyl substituted alkenes, which can be functionalized by free radical addition to the C,Cdouble bond. We have been able to add enolizable compounds, e. g. acetone, acetic acid and malonic acid to methyl oleate mediated by manga- nese(II1)acetate.