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Manganese-catalyzed reaction of gem-dibromoalkanes with Grignard reagents. Selective synthesis of alkenylsilanes

✍ Scribed by Hirotada Kakiya; Rie Inoue; Hiroshi Shinokubo; Koichiro Oshima

Publisher
Elsevier Science
Year
1997
Tongue
French
Weight
204 KB
Volume
38
Category
Article
ISSN
0040-4039

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✦ Synopsis

Treatment of dibromomethyltrialkylsilanes with butylmagnesium bromide in the presence of a catalytic amotmt of manga,aese.,0/) chloride provided (E)-l-trialkylsilyl-i-pentenes with high stereoselectivity in good yields.

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