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Manganese-Catalyzed Enantioselective Oxidation of C—H Bonds of Alkanes and Silyl Ethers to Optically Active Ketones.

✍ Scribed by Shun-Ichi Murahashi; Satoru Noji; Tatsuo Hirabayashi; Naruyoshi Komiya


Publisher
John Wiley and Sons
Year
2006
Weight
23 KB
Volume
37
Category
Article
ISSN
0931-7597

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✦ Synopsis


Abstract

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ChemInform Abstract: Manganese Catalyzed
✍ N. KOMIYA; S. NOJI; S.-I. MURAHASHI 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 32 KB 👁 1 views

Manganese Catalyzed Asymmetric Oxidation of Alkanes to Optically Active Ketones Bearing Asymmetric Center at the α-Position. -Symmetrical alkanes (II) and (IV) are oxidized with iodosobenzene/4phenylpyridine-N-oxide in the presence of catalytic chiral (salen)Mn(III) complexes (I) providing optically