Manganese Catalyzed Asymmetric Oxidation of Alkanes to Optically Active Ketones Bearing Asymmetric Center at the α-Position. -Symmetrical alkanes (II) and (IV) are oxidized with iodosobenzene/4phenylpyridine-N-oxide in the presence of catalytic chiral (salen)Mn(III) complexes (I) providing optically
✦ LIBER ✦
Manganese catalyzed asymmetric oxidation of alkanes to optically active ketones bearing asymmetric center at the α-position
✍ Scribed by Naruyoshi Komiya; Satoru Noji; Shun-Ichi Murahashi
- Book ID
- 108387084
- Publisher
- Elsevier Science
- Year
- 1998
- Tongue
- French
- Weight
- 227 KB
- Volume
- 39
- Category
- Article
- ISSN
- 0040-4039
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Influence of enolate geometry and struct
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Franklin A. Davis; Aurelia C. Sheppard; G.Sankar Lal
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⚖ 309 KB
The sfereoselectiviry for the asymmetric oxidation of enolafes to opfica//y active a-hydroxy ketones using (+)-( camphoryisulfonyi)oxaziridine is dependent on the enoiate substitution pattern, the solution structure of the enoiate and to a lesser extent the enoiate geometry Optically active a-hydrox