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Manganese carbonyl complexes of 2,5-dimethylbismolyl. The crystal and molecular structure of (η1-2,5-dimethylbismolyl) manganese pentacarbonyl

✍ Scribed by Arthur J. Ashe III; Jeff W. Kampf; Dhananjay B. Puranik


Publisher
Elsevier Science
Year
1993
Tongue
English
Weight
309 KB
Volume
447
Category
Article
ISSN
0022-328X

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## Abstract The dipyrroloimidazolyl ligand is found to bind the pentacarbonylmanganese group to its central ring __via__ a carbon‐metal σ‐bond. This bonding mode differs greatly from that of known imidazole complexes and from the pentahapto mode encountered with the isoelectronic fluorenyl ligand.