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Malonic ester and acetoacetic ester synthesis of 2-[11,14C]methyl-fatty acids

✍ Scribed by Koji Ogawa; Motoji Sasaki; Tadashi Nozaki


Book ID
108484375
Publisher
Elsevier Science
Year
1997
Tongue
English
Weight
475 KB
Volume
48
Category
Article
ISSN
0969-8043

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## Abstract In a first step, Ξ”1‐trans‐octenoic‐3‐^14^C acid was prepared by a Grignard reaction with BaCO~3~‐^14^C and 1‐bromo‐pentane, followed by reduction of the obtained hexanoic‐1‐^14^C acid to hexanal‐1‐^14^C via the n‐hexanol‐1‐^14^C. The produced hexanal‐1‐^14^C, by condensing with malonic