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Making and Breaking of P–P Bonds with Low-Valent Transition-Metal Complexes

✍ Scribed by Santiago Gómez-Ruiz; René Frank; Beatriz Gallego; Stefan Zahn; Barbara Kirchner; Evamarie Hey-Hawkins

Publisher
John Wiley and Sons
Year
2011
Tongue
English
Weight
733 KB
Volume
2011
Category
Article
ISSN
1434-1948

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Quantum mechanical ab initio calculations are reported at the MP2 level of theory with effective core potentials for the heavy atoms of the low-valent carbene complexes [(CO) 5 WCH 2 ] (1), [(CO) 5 WCF 2 ] (2), [(CO) 5 WCHF] (3), and [(CO) 5 WCH-(OH)] (4), and for the high-valent carbene complexes [