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Structure and Bonding of Low-Valent (Fischer-Type) and High-Valent (Schrock-Type) Transition Metal Carbyne Complexes

✍ Scribed by Sergei F. Vyboishchikov; Gernot Frenking


Publisher
John Wiley and Sons
Year
1998
Tongue
English
Weight
240 KB
Volume
4
Category
Article
ISSN
0947-6539

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Structure and Bonding of Low-Valent (Fis
✍ Sergei F. Vyboishchikov; Gernot Frenking πŸ“‚ Article πŸ“… 1998 πŸ› John Wiley and Sons 🌐 English βš– 266 KB πŸ‘ 1 views

Quantum mechanical ab initio calculations are reported at the MP2 level of theory with effective core potentials for the heavy atoms of the low-valent carbene complexes [(CO) 5 WCH 2 ] (1), [(CO) 5 WCF 2 ] (2), [(CO) 5 WCHF] (3), and [(CO) 5 WCH-(OH)] (4), and for the high-valent carbene complexes [