Magnetochemical study of solutions of tetraalkylammonium salts in D2O at different temperatures
β Scribed by Yu. V. Ergin; L. I. Kostrova; O. Ya. Samoilov
- Publisher
- SP MAIK Nauka/Interperiodica
- Year
- 1977
- Tongue
- English
- Weight
- 373 KB
- Volume
- 17
- Category
- Article
- ISSN
- 0022-4766
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π SIMILAR VOLUMES
A Raman spectroscopic study was carried out on aqueous solutions of R 4 NCl (R = methyl, ethyl and npropyl) at low temperatures and in the glassy state. The changes in the Raman OD stretching spectra with temperature, R 4 NCl and concentration are discussed in connection with hydrophobic hydration.
The spin-lattice relaxation times (T1) of D and 170 nuclei of D20 molecules in tetraalkylammonium bromides (R4NBr; R=Me, Et, Pr, Bu), dilute aqueous solutions were measured at the concentration of 0.2 to 1.0 mol/kg and at the temperature of 5 to 25 Β°C. The relative spin-lattice relaxation rate, R1/R