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Raman study of aqueous tetraalkylammonium chloride solutions at low temperatures

✍ Scribed by H. Kanno; A. Ohnishi; K. Tomikawa; Y. Yoshimura

Publisher: John Wiley and Sons
Year: 1999
Tongue: English
Weight: 173 KB
Volume: 30
Category: Article
ISSN: 0377-0486
DOI: 10.1002/(sici)1097-4555(199908)30:8<705::aid-jrs438>3.0.co;2-x

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✦ Synopsis

A Raman spectroscopic study was carried out on aqueous solutions of R 4 NCl (R = methyl, ethyl and npropyl) at low temperatures and in the glassy state. The changes in the Raman OD stretching spectra with temperature, R 4 NCl and concentration are discussed in connection with hydrophobic hydration. It is shown that a clathrate-like structure around alkyl groups develops with decreasing temperature. The formation of strong hydrogen bonds in aqueous R 4 NCl solution at low temperatures is closely connected with clathrate-like structure formation.

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