Wavelength and intensity of the luminescence of single-crystal cis-bis(2-phenylpyridine)platinum(II) depend on the temperature (1.7 6 T < 50 K) and on the strength of an applied magnetic field (H 6 5 T). The symmetry and spin-orbit splitting of the emitting states can thereby be determined
Magneto-optical evidence for two-level phosphorescence of the binuclear platinum(II) complex Ba2Pt2(H2P2O5)4
✍ Scribed by L. Bär; G. Gliemann
- Publisher
- Elsevier Science
- Year
- 1984
- Tongue
- English
- Weight
- 402 KB
- Volume
- 108
- Category
- Article
- ISSN
- 0009-2614
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Reexamination of the p~~~horescenc~ of\_Ba2Pt~&Plb0s)4 reveals that the ==fO K spechum is a superpotition of two electronic transitions [3A2U(Eu,AIUj-AIg] separaied by -40 cm -l. Each band displays a prominent 110 cm-' vibrational progression\_ Fran&-Condon analysis yields a 4l.25 S% distortion of t
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