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Magnetism of TTF-TCNQ and related compounds: Pressure effects

✍ Scribed by D. Jérome; G. Soda; J.R. Cooper; J.M. Fabre; L. Giral

Publisher
Elsevier Science
Year
1977
Tongue
English
Weight
656 KB
Volume
22
Category
Article
ISSN
0038-1098

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Electron transfer in TTF–TCNQ and relate
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The S(2p) binding energies have been measured at room temperature in TTF-TCNQ and related compounds. The results indicate an electron transfer of 1 .O % 0.5 electrons/molecule for TTF-TCNQ.

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The amount of charge transfer in TTF-TCNQ and related solid compleses was determined by the anzdysis of the S 2p peak shape in their X-ray photoelectron spectra. The amount of charge transfer is 0.56 i 0.05 in TTF-TCNQ. The molccular ratio of TTF+ in the TTF column is determined to be 0.71 i 0.05 in