Magnetism and structure of polymeric oxovanadium(IV) acetate and other polymeric oxovanadium(IV) complexes
β Scribed by D.R. Dakternieks; C.M. Harris; P.J. Milham; B.S. Morris; E. Sinn
- Publisher
- Elsevier Science
- Year
- 1969
- Weight
- 144 KB
- Volume
- 5
- Category
- Article
- ISSN
- 0020-1650
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π SIMILAR VOLUMES
A b s t r a c t Six new p-phthalato binuclear oxovanadium(1V) complexes, namely [(VO)z(PHTH)-(L)2]SO, (L denotes '2,2'-bipyridine (bpy); 1,lO-phenanthroline (phen); 4,4'-dimethyl-2,2'-bipyridine (Mezbpy); 5-nitrcz1 ,lO-phenanthroline (NOZ-phen); 5-chIo~1,lO-phenanthroline (C1-phen) and 5methyl-1,lO-
The aminoalcohol ligands diethanolamine (H 2 dea) and triethanolamine (H 3 tea) react with [VO(acac) 2 ] to yield the tetranuclear oxovanadium(IV) complexes [{VO(dea)} 2 -{VO(acac)} 2 (Β΅ 2 -OMe) 2 ] (1) and [{VO(Htea)} 2 {VO(acac)} 2 (Β΅ 2 -OMe) 2 ] (2). In the case of the potentially bridging aminoa
Light brown [VO(5-NO 2 salen)] ' 2H 2 O (1; H 2 (5-NO 2 salen)β«Ψβ¬N, N-di-5-nitrosalicylidene-1,2-ethanediamine) and orange [VO(5-NO 2 sal-meso-stien)] ' 0.5H 2 O (2; H 2 (5-NO 2 salmeso-stien) β«Ψβ¬ N,N-di-5-nitrosalicylidene-(R,S)(S,R)-1,2diphenyl-1,2-ethanediamine) which have linear chain structures