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Magnetic susceptibilities of protactinium(IV), uranium(IV) and neptunium(IV) tetraformates

✍ Scribed by H.J. Schenk; E.W. Bohres; K. Schwochau


Publisher
Elsevier Science
Year
1975
Weight
267 KB
Volume
11
Category
Article
ISSN
0020-1650

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πŸ“œ SIMILAR VOLUMES


PMR and magnetic susceptibility of tetra
✍ C. Miyake; H. Sakurai; S. Imoto πŸ“‚ Article πŸ“… 1975 πŸ› Elsevier Science 🌐 English βš– 279 KB

There are opposite opinions as to the geometrical structure of U(Iqpdikctonate in solution. Frcm the result of both PMR spectra and magnetic susceptibility in solution, a square antiprism with higher symmetry than a dodecahedron is considered to be the structure in solution.

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maxima at 135 and 142 L on the magnetic susceptxb&t> -tempemture curw, respectively+ Accurding to the Heisenbers model 2Jek Is obtained to be -94 and -99 cm-l, respectivelel). While magnetic exchange interaction in transition metal complexes has been extensively studied, uranium complex with such an